ChemicalBook > CAS DataBase List > 2,2'-Biphenol

2,2'-Biphenol

Product Name
2,2'-Biphenol
CAS No.
1806-29-7
Chemical Name
2,2'-Biphenol
Synonyms
BIPHENYL-2,2'-DIOL;2,2'-DIHYDROXYBIPHENYL;2 Biphenol;Orthodiphenol;2,2'-DIPHENOL;2,2'-BIPHENOL;O,O'-BIPHENOL;O,O'-DIPHENOL;2,2'-Biphenol;O,O'-Diphenole
CBNumber
CB2302883
Molecular Formula
C12H10O2
Formula Weight
186.21
MOL File
1806-29-7.mol
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2,2'-Biphenol Property

Melting point:
108-110 °C
Boiling point:
315 °C(lit.)
Density 
0.83
refractive index 
1.6086 (estimate)
Flash point:
154 °C
storage temp. 
Store below +30°C.
form 
Powder
pka
7.32±0.10(Predicted)
color 
Beige to grayish-beige
Water Solubility 
insoluble
BRN 
1638363
InChIKey
IMHDGJOMLMDPJN-UHFFFAOYSA-N
CAS DataBase Reference
1806-29-7(CAS DataBase Reference)
NIST Chemistry Reference
[1,1'-Biphenyl]-2,2'-diol(1806-29-7)
EPA Substance Registry System
2,2'-Biphenol (1806-29-7)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
37/38-41-36-22
Safety Statements 
26-39-36/37/39
WGK Germany 
2
RTECS 
DV4200000
8-9-23
Autoignition Temperature
324 °C
TSCA 
Yes
HS Code 
29029090
Toxicity
oms-hmn:lym 5 mmol/L CNREA8 45,2471,85
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H302Harmful if swallowed

H315Causes skin irritation

H318Causes serious eye damage

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.20154
Product name
Biphenyl-2,2′-diol
Purity
for synthesis
Packaging
50g
Price
$50.3
Updated
2024/03/01
Sigma-Aldrich
Product number
115819
Product name
2,2′-Biphenol
Purity
99%
Packaging
100g
Price
$70.4
Updated
2024/03/01
Sigma-Aldrich
Product number
115819
Product name
2,2′-Biphenol
Purity
99%
Packaging
500g
Price
$167.4
Updated
2024/03/01
TCI Chemical
Product number
B0813
Product name
2,2'-Dihydroxybiphenyl
Purity
>98.0%(GC)
Packaging
25g
Price
$49
Updated
2024/03/01
TCI Chemical
Product number
B0813
Product name
2,2'-Dihydroxybiphenyl
Purity
>98.0%(GC)
Packaging
100g
Price
$147
Updated
2024/03/01
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2,2'-Biphenol Chemical Properties,Usage,Production

Chemical Properties

Beige to greyish-beige powder

Uses

2,2'-Dihydroxybiphenyl, is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.

Production Methods

2,2'-Dihydroxybiphenyl is obtained by alkaline fusion of biphenylene oxide at ca. 300 ℃ (sometimes catalyzed by fluorene or carbazole) or by debutylation of 3,3',5,5'-tetra-tert-butyl-2,2'-dihydroxybiphenyl, which itself is produced by the oxidative coupling of 2,4-di-tert-butylphenol. 2,2'-Dihydroxy-5,5'-dimethylbiphenyl can be synthesized accordingly.

Definition

ChEBI: A member of the class of hydroxybiphenyls carrying hydroxy groups at positions 2 and 2'.

Safety Profile

Poison by intraperitoneal andintravenous routes. Human mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating fumes.

Purification Methods

Crystallise the biphenyl repeatedly from toluene, then sublime it at 60o/10-4mm. [Beilstein 6 IV 6645.]

2,2'-Biphenol Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2,2'-Biphenol manufacturers

Henan Suikang Pharmaceutical Co.,Ltd.
Product
2,2-biphenol 1806-29-7
Price
US $0.00/kg
Min. Order
25kg
Purity
97.0%~102.0%
Supply Ability
10tons
Release date
2024-04-28
Junwee Chemical co., Ltd.
Product
Biphenyl-2,2'-diol 1806-29-7
Price
US $0.00/kg
Min. Order
25kg
Purity
99%min.
Supply Ability
200 tons
Release date
2024-03-25
Henan Fengda Chemical Co., Ltd
Product
2,2'-Biphenol 1806-29-7
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-24

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